New Insights into Perfluorinated Sulfonic-Acid Ionomers

Publication Type

Journal Article

Date Published

08/2017

Authors

Ahmet Kusoglu, Adam Z. Weber

DOI

Abstract

In this comprehensive review, recent progress and developments on perfluorinated sulfonic-acid (PFSA) membranes have been summarized on many key topics. Although quite well investigated for decades, PFSA ionomers’ complex behavior, along with their key role in many emerging technologies, have presented significant scientific challenges but also helped create a unique cross-disciplinary research field to overcome such challenges. Research and progress on PFSAs, especially when considered with their applications, are at the forefront of bridging electrochemistry and polymer (physics), which have also opened up development of state-of-the-art in situ characterization techniques as well as multiphysics computation models. Topics reviewed stem from correlating the various physical (e.g., mechanical) and transport properties with morphology and structure across time and length scales. In addition, topics of recent interest such as structure/transport correlations and modeling, composite PFSA membranes, degradation phenomena, and PFSA thin films are presented. Throughout, the impact of PFSA chemistry and side-chain is also discussed to present a broader perspective.

Journal

Chemical Reviews

Volume

117

Year of Publication

2017

Issue

3

ISSN

0009-2665

Organization

Research Areas

Laboratory

LBNL

Type

Analysis, Durability, Integration, Materials, Special Articles, User Facilities