Subsecond Morphological Changes in Nafion during Water Uptake Detected by Small-Angle X-ray Scattering

Publication Type

Journal Article

Date Published

01/2012

Authors

Ahmet Kusoglu, Miguel A. Modestino, Alexander Hexemer, Rachel A Segalman, Adam Z. Weber

DOI

Abstract

The ability of the Nafion membrane to absorb water rapidly and create a network of hydrated interconnected water domains provides this material with an unmatched ability to conduct ions through a chemically and mechanically robust membrane. The morphology and composition of these hydrated membranes significantly affects their transport properties and performance. This work demonstrates that differences in interfacial interactions between the membranes exposed to vapor or liquid water can cause significant changes in kinetics of water uptake. In situ small-angle X-ray scattering (SAXS) experiments captured the rapid swelling of the membrane in liquid water with a nanostructure rearrangement on the order of seconds. For membranes in contact with water vapor, morphological changes are four orders-of-magnitude slower than in liquid water, suggesting that interfacial resistance limits the penetration of water into the membrane. Also, upon water absorption from liquid water, a structural rearrangement from a distribution of spherical and cylindrical domains to exclusively cylindrical-like domains is suggested. These differences in water-uptake kinetics and morphology provide a new perspective into Schroeder's paradox, which dictates a different water content for vapor- and liquid-equilibrated ionomers at unit activity. The findings of this work provide critical insights into the fast kinetics of water absorption of the Nafion membrane, which can aid in the design of energy conversion devices that operate under frequent changes in environmental conditions.

Journal

ACS Macro Letters

Volume

1

Year of Publication

2012

Issue

1

ISSN

2161-1653

Organization

Research Areas

Laboratory

LBNL

Type

Collaborations, Integration, Legacy Papers, Materials, Special Articles, User Facilities